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Calcium Nitrate Tetrahydrate [Ca(NO₃)₂·4H₂O] Industry Whitepaper

A deep dive into synthesis parameters, industrial value chains, and thermodynamic characteristics

1. Technical Profile & Chemical Behavior

Calcium Nitrate Tetrahydrate, scientifically denoted as Ca(NO₃)₂·4H₂O, represents a critical inorganic compound containing crucial mineral elements—nitrogen and calcium. As a monoclinic crystalline solid, it displays a molecular weight of 236.15 g/mol. Thanks to its precise tetrahydrate crystal form, it exhibits unique thermodynamic stability, melting at approximately 42.7°C while releasing its coordinate crystal water molecules progressively upon further heating. This chemical trait makes it a valuable precursor for solar energy salt formulations, chemical catalysts, and high-performance agricultural agents.

Unlike anhydrous forms, the tetrahydrate variant provides rapid dissolution dynamics with a highly endothermic heat of solution. This makes it an ideal reagent in operations where rapid cooling and fast dissolution are required. In aqueous systems, it yields free calcium ions (Ca²⁺) and nitrate anions (NO₃⁻) instantly, which are directly bioavailable to plants or ready to participate in polymerization reactions in concrete engineering.

Parameters Standard Specification (Industrial Grade) High-Purity Electronic Grade
Chemical Formula Ca(NO₃)₂·4H₂O Ca(NO₃)₂·4H₂O
Assay (Purity) ≥ 99.0% ≥ 99.7%
Water Insoluble Matter ≤ 0.05% ≤ 0.01%
Iron (Fe) Content ≤ 0.002% ≤ 0.0005%
Heavy Metals (as Pb) ≤ 0.001% ≤ 0.0002%
pH Value (5% Solution) 5.0 - 7.0 5.5 - 6.5

2. Global Procurement Challenges & Intent Analysis

Global procurement managers seeking Calcium Nitrate Tetrahydrate face multi-layered challenges. The material is highly hygroscopic; poor moisture barriers during transit can cause caking or liquefaction, rendering the batch unusable for precision manufacturing processes. Industrial buyers must evaluate the factory's anti-caking technologies, packaging specifications (such as heavy-duty PE-lined bags), and supply-chain stability.

Furthermore, security of supply is heavily tied to upstream nitric acid pricing and environmental policies in key manufacturing zones. Buying directly from integrated Chinese factories like Shanxi Vojin New Materials ensures price stability, stable purity, and compliance with global regulatory baselines.

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Explore our core inorganic chemical production divisions

Nitrates Series

Nitrates Series

High purity potassium, sodium, and calcium nitrates tailored for critical industrial operations and molten salt energy storage.

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Fertilizer Series

Fertilizer Series

100% water-soluble formulations designed to provide immediate calcium, nitrogen, and potassium nutrition for agricultural crop cycles.

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By-Products

By-Products

Industrial co-products and chemical variants optimized for reuse and sustainable processing within green production loops.

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Key Applications of Ca(NO₃)₂·4H₂O

Powering global industries from clean energy storage to advanced agriculture

Thermal Energy Storage

Utilized as a critical compound in ternary molten salt mixtures (Solar Salt systems) to lower eutectic melting points and enhance thermodynamic stability in CSP plants.

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Display Devices Manufacturing

Serves as a vital coagulant and surface treating agent in the production of specialized glass substrates and display screen layers.

Industry Steam & Heating

Plays a vital role in industrial heating, coal conversion processes, and regional green steam projects utilizing molten salt heat storage systems.

Agricultural Technology

Acts as the ideal base for 100% water-soluble fertilizers, supplying crops with readily available calcium and nitrate-nitrogen to eliminate deficiency symptoms.

Driven Since 2000: High-Tech Chemical Pioneers

SHANXI VOJIN NEW MATERIALS CO., LTD.

Driven since 2000, we have been committed to the entrepreneurial spirit and passion for innovation. Our team takes pride in delivering dependable products and services with a quality distinction in thermal energy storage & water-soluble fertilizer industries globally.

By integrating manufacturing facilities in the heart of China's coal-chemical resources base, we secure low-cost chemical feedstocks while utilizing state-of-the-art crystallization and environmental control systems. This allows us to guarantee consistent delivery of calcium nitrate tetrahydrate, industrial potassium nitrate, and high-purity molten salts to all corners of the globe.

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Vojin Manufacturing Plant Nitrate Products Line

We Manufacture Renewable Products

Our years of manufacturing experience and refined products provide you with better performance

15+
Years Experience
600,000 Ton annual capacity for global demands.
50+
Product Breakdown
Exporting high-quality chemicals to over 40 countries.
80+
Advanced Solutions
Operating across a manufacturing area of approx 1000 acres.
2010
Established Year
Over a decade of institutional innovation and market leadership.

Industrial Solution Architecture & Compliance

How Vojin solves critical engineering bottlenecks for global operations

3. Molten Salt Energy Storage & CSP Optimization

In concentrating solar power (CSP) generation, binary molten salt blends of Sodium Nitrate and Potassium Nitrate are commonly used. However, their high melting temperature (approx 220°C) poses freeze-up risks in pipeline loops. Incorporating high-grade Calcium Nitrate Tetrahydrate reduces the melting point to about 130°C. Lowering this operational threshold minimizes parasite energy required for heating systems, while significantly boosting overall solar thermal conversion efficiencies.

4. Localization, Global Regulatory Standards & REACH compliance

Vojin understands that chemical compliance represents an absolute baseline for North American and European buyers. We maintain full REACH pre-registration and strictly adhere to international hazard communications standard mandates (GHS). Every shipment is accompanied by detailed Safety Data Sheets (SDS), custom hazard classifications, and compliance validation. Through localized partnerships, our customers receive fast custom clearances, integrated warehouse drop-shipping options, and direct technical service.

5. Next-Gen Agricultural Water-Soluble Fertilizers

In modern precision drip irrigation and hydroponics, Calcium Nitrate is the only practical, highly soluble source of plant-available calcium. Because calcium is non-mobile in plant vascular tissues, continuous root-zone delivery is essential. Our low-ammonium, high-calcium tetrahydrate crystals dissolve instantly without leaving particulates that clog micro-emitters. By eliminating heavy metals and chloride ions, Vojin products ensure optimal osmotic balance for high-yield food crop operations.

Enterprise Advantages

Why leading global enterprises choose Shanxi Vojin New Materials

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Experience

Integrated experience on exporting operation Always assure your customers good quality.

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Production

Annual output 600,000 Ton Molten salts. High stability synthesis lines running 24/7.

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Services

Experienced technology skill & service team Quick response to our customers globally.

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Rich choices

Multiple items for selection such as KNO3, NaNO3 to meet various need of customers.

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Frequently Asked Questions

Technical answers regarding Calcium Nitrate Tetrahydrate

Q1: What is the differences between Calcium Nitrate Tetrahydrate and the anhydrous form?
Calcium Nitrate Tetrahydrate (Ca(NO₃)₂·4H₂O) contains 4 water molecules per unit crystal structure. It melts at a low temperature of 42.7°C, which facilitates high-purity dissolution in energy storage manufacturing. Anhydrous Calcium Nitrate contains no water crystallization, has a higher processing melting point, and absorbs environmental moisture aggressively, making packaging more critical.
Q2: How does Vojin prevent caking in Calcium Nitrate during international logistics?
Our factory integrates advanced crystallization processes that produce uniform crystal size distributions, reducing surface contact area. We also utilize multi-layered packaging including PE liners and moisture-barrier outer bags to protect the material from ambient humidity during maritime transport.
Q3: Is Calcium Nitrate Tetrahydrate classified as a hazardous chemical?
Typically, pure calcium nitrate tetrahydrate is classified under UN 1454, Class 5.1 Oxidizer. Our shipping documentation conforms fully to GHS regulations, and we ensure compliance with IMDG code provisions for safe maritime transit.
Q4: What is the maximum annual production capacity of Shanxi Vojin?
Shanxi Vojin possesses a total manufacturing capacity of over 600,000 tons of inorganic nitrate series annually, making us a reliable partner for large-scale procurement demands.
Q5: Can you customize purity grades for technical and semiconductor applications?
Yes, our processing lines can refine high-purity grades (up to 99.7% and higher) with extremely low heavy metals and water-insoluble matter, making them suitable for electronic display manufacturing.

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